Research
Energy Materials, Batteries, Catalysis, Operando Studies, Neutron Scattering
Interests
My expertise is in synthesising scalably made nanomaterials and embedding them into energy devices for increased performance. These include devices such as Li-ion batteries, Na-ion batteries and hydrogen fuel cells. I also develop novel operando techniques for probe the materials in energy devices as they work. My work takes place in the lab at Queen Mary or at neutron or synchrotron X-ray sources such as ISIS and Diamond.
Interests
Our mission is to pioneer the development of new materials and integrate them into innovative applications and devices. We focus on addressing critical challenges in energy storage, environmental sustainability, and advanced manufacturing.
Our vision is to be a leading hub for groundbreaking materials research and to drive the transition to a more sustainable and technologically advanced future.
Research Themes and Areas of Interest
Core Research Areas: Our lab specializes in the interdisciplinary fields of material science, chemistry, and physics, with a primary focus on designing novel materials and leveraging them for practical applications.
Current Projects
*Operando Neutron Scattering of Electrochemical Devices: Utilizing advanced neutron scattering techniques to understand the in-situ behavior of electrochemical devices, enhancing their performance and durability.
*Nanomaterial Production and Characterisation: Synthesizing new nanomaterials and characterizing their properties for various industrial and technological applications.
*Carbon Dioxide Reduction: Developing innovative materials and methods for efficient CO2 capture and conversion, contributing to the reduction of greenhouse gas emissions.
*Hydrogen Storage Materials: Creating safe and efficient materials for hydrogen storage, a critical component in the shift towards clean energy.
*Suzuki Coupling Electrocatalysis: Enhancing the efficiency of Suzuki coupling reactions through novel electrocatalysts, impacting pharmaceuticals and fine chemicals manufacturing.
*Solid State Electrolytes: Designing high-performance solid electrolytes for safer and more efficient batteries.
*Li and Na-ion Battery Electrodes: Developing advanced electrode materials for lithium and sodium-ion batteries to improve energy density and battery life.
Techniques and Technologies
Our lab is equipped with state-of-the-art facilities to push the boundaries of material science. We have the facilites to manufacture and synthesise materials in air-free environemnts, which is important for many energy technologies including various types of batteries.
In terms of battery testing we have an 80 channel battery cycler and a 32 channel battery cycler that can do more advanced analysis including EIS (Electrochemical Impedance Spectroscopy).
Our group are also regular users of the synchotron at Diamond light source and of neutron scattering at ISIS neutron and muon source, both of which are in Oxfordshire.
Publications

Publications of specific relevance to the Centre for Sustainable Engineering
2025
Intermediate-range solvent templating and counterion behaviour at charged carbon nanotube surfacesDi Mino C Headen TF Basma NS Buckley DJ Cullen PL Wilding MC Shaffer MSP Skipper NT et al.
Nature Nanotechnology,
Springer Nature vol. 20 (5), 639-645.
21-02-2025
Hydrogen Induced Phase Transition in TiZrNbHfV1–x Ta x High Entropy AlloysGreaves F Bouzidi A Perrière L Vaughan G Nassif V Laversenne L Borgschulte A Martins ML et al.
The Journal of Physical Chemistry C,
American Chemical Society (Acs) vol. 129 (6), 2904-2912.
31-01-20252024
Investigating the effect of Fe–N 5 configuration in the oxygen reduction reaction using N-heterocycle functionalized carbon nanotubesLi Q Zhao Q Pedersen A Zhang M Lin Z Xu Y Cullen PL Sapelkin A et al.
Journal of Materials Chemistry A,
Royal Society of Chemistry (Rsc) vol. 12 (41), 28074-28084.
26-09-2024
Controlling nanocluster growth through nanoconfinement: the effect of the number and nature of metal–organic framework functionalitiesKing J Lin Z Zanca F Luo H Zhang L Cullen P Danaie M Hirscher M et al.
Physical Chemistry Chemical Physics,
Royal Society of Chemistry 01-01-20242023
Novel High Entropy Sulfides as High Capacity Lithium-ion Cathode MaterialsSeemungal L Li S Crespo M Reece M Cullen P
Proceedings of the MATSUS Fall 2023 Conference.
18-07-2023
2023 roadmap for potassium-ion batteriesXu Y Titirici M Chen J Cora F Cullen PL Edge JS Fan K Fan L et al.
Jphys Energy,
Iop Publishing vol. 5 (2)
06-04-2023
Ex Situ Characterization of 1T/2H MoS2 and Their Carbon Composites for Energy Applications, a ReviewMarinov AD Bravo Priegue L Shah AR Miller TS Howard CA Hinds G Shearing PR Cullen PL et al.
Acs Nano,
American Chemical Society vol. 17 (6), 5163-5186.
16-03-20232022
A new high: Cannabis as a budding source of carbon-based materials for electrochemical power sourcesRana ZI Shah AR Llewellyn AV Mazloomian K McAlernon P Miller TS Cullen PL Shearing PR et al.
Current Opinion in Electrochemistry,
Elsevier vol. 31
01-02-20222021
Neutron studies of Na-ion battery materialsShah AR Shutt RRC Smith K Hack J Neville TP Headen TF Brett DJL Howard CA et al.
Jphys Materials vol. 4 (4)
27-09-2021
A novel fuel cell design for operando energy-dispersive x-ray absorption measurementsLeach AS Hack J Amboage M Diaz-Moreno S Huang H Cullen PL Wilding M Magliocca E et al.
Journal of Physics Condensed Matter,
Iop Publishing vol. 33 (31)
16-06-20212020
Realising the electrochemical stability of graphene: scalable synthesis of an ultra-durable platinum catalyst for the oxygen reduction reaction.Angel GMA Mansor N Jervis R Rana Z Gibbs C Seel A Kilpatrick AFR Shearing PR et al.
Nanoscale 29-06-2020
Use of X-ray computed tomography for understanding localised, along-the-channel degradation of polymer electrolyte fuel cellsHack J Rasha L Cullen PL Bailey JJ Neville TP Shearing PR Brandon NP Brett DJL
Electrochimica Acta vol. 352
23-05-20202019
Lignin-derived electrospun freestanding carbons as alternative electrodes for redox flow batteriesJorge Sobrido A Jervis R Crespo Ribadeneyra M Grogan L Au H Schlee P Herou S Neville T et al.
Carbon,
Elsevier 06-11-2019
The liquid structure of the solvents dimethylformamide (DMF) and dimethylacetamide (DMA)Basma N Cullen PL Clancy AJ Shaffer MSP Skipper NT Headen TF Howard CA
Molecular Physics,
Informa Uk Limited vol. 117 (22), 3353-3363.
16-08-2019
Solvation of Na– in the Sodide Solution, LiNa·10MeNH2Seel AG Holzmann N Imberti S Bernasconi L Edwards PP Cullen PL Howard CA Skipper NT
The Journal of Physical Chemistry B,
American Chemical Society (Acs) vol. 123 (25), 5337-5342.
30-05-2019
Production of phosphorene nanoribbonsWatts MC Picco L Russell-Pavier FS Cullen PL Miller TS Bartuś SP Payton OD Skipper NT et al.
Nature,
Nature Research vol. 568 (7751), 216-220.
11-04-20192018
The structures of liquid pyridine and naphthalene: The effects of heteroatoms and core size on aromatic interactionsHeaden TF Cullen PL Patel R Taylor A Skipper NT
Physical Chemistry Chemical Physics vol. 20 (4), 2704-2715.
01-01-20182017
Single Crystal, Luminescent Carbon Nitride Nanosheets Formed by Spontaneous DissolutionMiller TS Suter TM Telford AM Picco L Payton OD Russell-Pavier F Cullen PL Sella A et al.
Nano Letters vol. 17 (10), 5891-5896.
11-10-2017
Trajectory of the selective dissolution of charged single-walled carbon nanotubesBuckley DJ Hodge SA Marco MD Hu S Anthony DB Cullen PL Mckeigue K Skipper NT et al.
Journal of Physical Chemistry C vol. 121 (39), 21703-21712.
05-10-2017
Investigation of Hot Pressed Polymer Electrolyte Fuel Cell Assemblies via X-ray Computed TomographyMeyer Q Mansor N Iacoviello F Cullen PL Jervis R Finegan D Tan C Bailey J et al.
Electrochimica Acta,
Elsevier Bv vol. 242, 125-136.
01-07-2017
Ionic solutions of two-dimensional materialsCullen PL Cox KM Bin Subhan MK Picco L Payton OD Buckley DJ Miller TS Hodge SA et al.
Nature Chemistry vol. 9 (3), 244-249.
01-03-20172014
Probing the charging mechanisms of carbon nanomaterial polyelectrolytesHodge SA Tay HH Anthony DB Menzel R Buckley DJ Cullen PL Skipper NT Howard CA et al.
Faraday Discussions,
Royal Society of Chemistry (Rsc) vol. 172, 311-325.
01-01-20142013
Multielement NMR Studies of the Liquid–Liquid Phase Separation and the Metal-to-Nonmetal Transition in Fluid Lithium– and Sodium–Ammonia SolutionsLodge MTJH Cullen P Rees NH Spencer N Maeda K Harmer JR Jones MO Edwards PP
The Journal of Physical Chemistry B,
American Chemical Society (Acs) vol. 117 (42), 13322-13334.
13-09-20132012
Structure and Morphology of Charged Graphene Platelets in Solution by Small-Angle Neutron ScatteringMilner EM Skipper NT Howard CA Shaffer MSP Buckley DJ Rahnejat KA Cullen PL Heenan RK et al.
Journal of The American Chemical Society,
American Chemical Society (Acs) vol. 134 (20), 8302-8305.
14-05-2012
Long-range solvent templating and counterion behavior at a charged, nanoscale surfacesDi Mino C Headen T Basma N Buckley D Cullen P Wilding M Shaffer M Skipper N et al.
In
Chemrxiv